SpeakingFaces is a publicly-available large-scale dataset developed to support multimodal machine learning research in contexts that utilize a combination of thermal, visual, and audio data streams; examples include human-computer interaction (HCI), biometric authentication, recognition systems, domain transfer, and speech recognition. SpeakingFaces is comprised of well-aligned high-resolution thermal and visual spectra image streams of fully-framed faces synchronized with audio recordings of each subject speaking approximately 100 imperative phrases.